7305-13-7Relevant academic research and scientific papers
AlCl3-promoted thiolation of acyl C-H bonds with arylsulfonyl hydrazides
Chen, Jie,Mao, Jincheng,He, Yue,Shi, Daqing,Zou, Binyang,Zhang, Guoqi
supporting information, p. 9496 - 9500 (2015/11/18)
AlCl3-promoted thiolation of acyl C-H bonds with arylsulfonyl hydrazides was developed, which represents an effective synthesis of S-aryl thiocarbamates via C-S bond formation reaction.
Cu(OAc)Catalyzed Thiolation of Acyl C-H bonds with thiols using TBHP as an oxidant
Yuan, Yan-Qin,Guo, Sheng-Rong,Xiang, Jian-Nan
supporting information, p. 443 - 448 (2013/03/29)
Cu(OAc)promoted TBHP oxidative coupling reaction of formamides with thiols successfully proceeded through direct C-H bond activation of formamides. The corresponding S-phenyl dialkyl thiocarbamate compounds were formed with high yield under solvent-free c
Novel cruciform structures as model compounds for coordination induced single molecule switches
Grunder, Sergio,Huber, Roman,Wu, Songmei,Schoenenberger, Christian,Calame, Michel,Mayor, Marcel
scheme or table, p. 140 - 144 (2011/08/04)
We have synthesized various molecular cruciforms consisting of two different crossing π-systems and comprising crosswise arranged thiol- and pyridine-anchor groups. With these model compounds we strive towards the investigation of a new switching concept based on the potential dependent coordination of pyridines to gold electrodes in an electrochemical set-up. Integration of these cruciform molecules between both electrodes of a mechanically controlled break junction in a liquid environment gave insight into their single molecule transport properties. These studies allowed individual transport characteristics to be assigned to the bar subunits of the cruciforms but also revealed the remaining experimental challenges to realize the suggested switching concept. Schweizerische Chemische Gesellschaft.
The Newman-Kwart rearrangement re-evaluated by microwave synthesis
Moseley, Jonathan D.,Sankey, Rosalind F.,Tang, Olivier N.,Gilday, John P.
, p. 4685 - 4689 (2007/10/03)
The Newman-Kwart rearrangement (NKR) has been re-evaluated by microwave heating. Microwave technology has proven to be ideal for investigating this high temperature rearrangement and facilitated the confirmation of many aspects of this valuable reaction.
