73087-01-1

Basic information

• Product Name: L-methyl 2-N-benzyloxycarbonyl-aminoxy-3-phenyl propanoate
• CAS NO: 73087-01-1
• Molecular Weight: 329.353
• Mol File: 73087-01-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: L-methyl 2-N-benzyloxycarbonyl-aminoxy-3-phenyl propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: L-methyl 2-N-benzyloxycarbonyl-aminoxy-3-phenyl propanoate(73087-01-1)
• EPA Substance Registry System: L-methyl 2-N-benzyloxycarbonyl-aminoxy-3-phenyl propanoate(73087-01-1)

Safety Data

• Hazardous Substances Data: 73087-01-1(Hazardous Substances Data)

Upstream product

• 35016-63-8 (S)-2-bromo-3-phenylpropionic acid 
• 63-91-2 L-phenylalanine 
• 3426-71-9 Benzyl N-hydroxycarbamate 
• 124916-61-6 (S)-2-bromo-3-penylpropanoic acid methyl ester 
• 67-56-1 methanol 

Relevant articles and documents

Synthesis and characterization of chiral N-O turns induced by α-aminoxy acids

Chiral α-aminoxy acids of various side chains were synthesized with high optical purity starting from chiral α-amino acids. The conformations of diamides 13a-e, 15, and 16 were probed by using NMR, FT-IR, and CD spectroscopic methods as well as X-ray crystallography. The right-handed turns with eight-membered-ring intramolecular hydrogen bonds between adjacent residues (called the N-O turns) were found to be preferred for D-aminoxy acid residues, and they were independent of the side chains. The rigid chiral N-O turns should have great potential in molecular design.