73088-68-3

Basic information

• Product Name: (1'R)-(2E)-3-methyl-3-(4'-methylcyclohexen-3'-yl)-propen-2-al-1
• Synonyms: (1'R)-(2E)-3-methyl-3-(4'-methylcyclohexen-3'-yl)-propen-2-al-1
• CAS NO: 73088-68-3
• Molecular Weight: 164.247
• Mol File: 73088-68-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1'R)-(2E)-3-methyl-3-(4'-methylcyclohexen-3'-yl)-propen-2-al-1(CAS DataBase Reference)
• NIST Chemistry Reference: (1'R)-(2E)-3-methyl-3-(4'-methylcyclohexen-3'-yl)-propen-2-al-1(73088-68-3)
• EPA Substance Registry System: (1'R)-(2E)-3-methyl-3-(4'-methylcyclohexen-3'-yl)-propen-2-al-1(73088-68-3)

Safety Data

• Hazardous Substances Data: 73088-68-3(Hazardous Substances Data)

Upstream product

• 77614-31-4 (R)-3-(4-methyl-cyclohex-3-enyl)-but-3-enal 
• 5989-27-5 D-limonene 
• 77614-30-3 (R)-(+)-3-(4-methyl-3-cyclohexen-1-yl)-3-buten-1-ol 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 77614-32-5 methyl (1'R)-(2E,6E)-3,7-dimethyl-7-(3'-bromo-4'-hydroxy-4'-methylcyclohexyl)-heptadien-2,6-oate 
• 77647-40-6 methyl (1'R)-(2Z,6E)-3,7-dimethyl-7-(3'-bromo-4'-hydroxy-4'-methylcyclohexyl)-heptadien-2,6-oate 
• 77647-37-1 methyl (1'R)-(2E,6E)-3,7-dimethyl-7-(4'-methylcyclohexen-3'-yl)-heptadien-2,6-oate 
• 77647-38-2 methyl(1'R)-(2Z,6E)-3,7-dimethyl-7-(4'-methylcyclohexen-3'-yl)heptadien-2,6-oate 
• 77647-36-0 (1'R)-(5E)-6-methyl-6-(4'-methylcyclohexen-3'-yl)hexen-5-one-2 
• 70286-27-0 (R)(E)-3-<4-Methyl-cyclohex-3-enyl>-but-2-enylbromid 
• 262290-97-1 (1R)-5-[(1S)-3-Hydroxy-1,5-dimethylhexyl]-2-methylenecyclohexanol 
• 262290-96-0 (2S)-2-[(1R)-4-Methylcyclohex-3-enyl]-6-methylheptan-4-ol 
• 128300-30-1 (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal 
• 26575-87-1 (+)-epijuvabione 
• 26091-09-8 (+)-Epitodomatuic acid 
• 26462-78-2 (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde 
• 262290-92-6 (S)-3-((R)-4-Methyl-cyclohex-3-enyl)-butan-1-ol 
• 26294-59-7 (E)-α-atlantone 

Relevant articles and documents

Baker's yeast mediated enantioselective synthesis of the bisabolene sesquiterpenes (+)-epijuvabione and (-)-juvabione

Fermenting baker's yeast converts the unsaturated aldehydes 7 and 11 into the saturated alcohols 8 and 12, respectively. The microbial saturation of the double bond proceeds in high chemical yields and the stereoselectivity of the reduction is strongly influenced by the E:Z ratio of the substrate. Enantiopure 8 and 12 are chiral building blocks for the synthesis of bisabolene sesquiterpenes and their usefulness is shown in the preparation of (+)-epijuvabione 1 and (-)-juvabione 3.