73090-40-1

Basic information

• Product Name: 3-chloro-1-(phenylselanyl)propane
• Synonyms: 3-chloro-1-(phenylselanyl)propane
• CAS NO: 73090-40-1
• Molecular Weight: 233.599
• Mol File: 73090-40-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-chloro-1-(phenylselanyl)propane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-chloro-1-(phenylselanyl)propane(73090-40-1)
• EPA Substance Registry System: 3-chloro-1-(phenylselanyl)propane(73090-40-1)

Safety Data

• Hazardous Substances Data: 73090-40-1(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 109-70-6 1.3-chlorobromopropane 
• 6940-76-7 1-iodo-3-chloro-propane 
• 2179-79-5 phenyl selenocyanate 

Downstream Products

• 122184-76-3 1-iodo-3-(phenylselanyl)propane 
• 191542-46-8 1-<3-(phenylselanyl)propyl>-2-(phenylsulfonyl)-1H-imidazole 
• 191542-43-5 1-<3-(phenylselanyl)propyl>-2-(phenylsulfanyl)-1H-benzimidazole 
• 191542-40-2 1-<3-(phenylselanyl)propyl>-2-tosyl-1H-imidazole 
• 1237786-98-9 C₂₆H₂₆N₄Se₂ 
• 1237787-02-8 C₂₆H₂₆N₄Se₂ 
• 1384457-32-2 C₁₃H₁₇N₂Se⁽¹⁺⁾*Cl^(1-) 

Relevant articles and documents

Oxidation of alcohols to aldehydes and ketones using selenium ionic liquid

A new type of ionic liquid supported selenium reagents were synthesized and found to be an excellent catalyst in the oxidation of alcohols to aldehydes and ketones in the presence of 30% H2O2. The predictable solubility of ionic liquids allows an easy separation of the oxidation products from the reaction mixture. Furthermore, the oxidation reaction can be carried out using an ionic liquid as the solvent, and the ionic liquid-supported selenium reagents can be recycled and used for four times with a little decrease in catalytic performance.

Radical cyclisations of imines and hydrazones

Radical cyclisation of sp3 carbon-centred radicals onto imines and hydrazones provides a new method for the synthesis of 5- and 6-membered ring nitrogen heterocycles. Cyclisation onto the electrophilic carbon of the C=N group and 5-exo stereoelectronic selectivity are the dominating mechanistic parameters. The C-centred radical intermediates were generated from benzeneselenyl precursors using Bu3SnH.