73110-83-5

Upstream product

• 34591-41-8 1-phenyl-3-(2'-hydroxy-5'-methoxyphenyl)-1-propene 
• 2327-99-3 1-phenylpropadiene 
• 150-76-5 4-methoxy-phenol 
• 179749-31-6 (5-methoxy-2-(methoxymethoxy)phenyl)-methan-1-ol 
• 93-02-7 2,5-dimethoxybenzaldehyde 
• 73220-20-9 5-methoxy-2-(methoxymethoxy)benzaldehyde 
• 672-13-9 2-hydroxy-5-methoxybenzaldehyde 
• 100-42-5 styrene 
• 1311270-92-4 5-methoxy-2-(methoxymethoxy)benzyl acetate 
• 1122-95-8 sodium 4-methoxyphenolate 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 

Relevant academic research and scientific papers

Excited state interactions in phenol/olefin bichromophoric compounds: Direct detection of an intramolecular exciplex

The emission from an intramolecular exciplex detected in trans-4-methoxy-2-(3-phenyl-2-propenyl)phenol (1) is the first direct evidence for the excited state interchromophoric interaction in phenol-styrene systems.

Regioselective Domino Synthesis of 2-Alkylflavans via Hidden Br?nsted Acid Catalysis

A range of alkyl-substituted flavans, which are important structural elements in natural products and pharmaceutical molecules, were prepared by successive hidden Br?nsted acid catalyzed domino reaction, intermolecular hydroarylation, and intramolecular hydroalkoxylation. 1,1-Disubstituted allenes were activated under mild acidic AgOTf/t-BuCl condition to initiate the regioselective Friedel-Crafts reaction with phenol derivatives, and the consecutive reaction triggered by the 6 -endo cyclization led to the formation of a new type of 2-alkylflavan. Mechanistic study of the reaction intermediates and control experiments support the catalytic pathway and advantage of hidden Bronsted acid catalysis.

Pt(IV)-catalyzed generation and [4+2]-cycloaddition reactions of o-quinone methides

Novel intermolecular and intramolecular generations of ortho-quinone methides and their formal [4+2]-cycloaddition reactions with olefins catalyzed by PtCl4 and AuCl3 under mild conditions have been developed. Good to excellent yields (up to 99%) and diastereoselectivity (up to >99:1) of the chromans were obtained. PtCl4 was found to be effective and compatible with various functional groups present in the substrates. A mechanism accounting for its catalytic cycle is proposed and discussed.

Intramolecular excited-state interactions in phenol-styrene bicromophoric systems: A photochemical and photophysical study

The intramolecular excited state interaction between phenol and styrene in a series of trans-2-cinnamylphenols bearing electron-donating substituents at the phenolic ring has been directly observed as an exciplex emission in acetonitrile. The photochemica