7313-70-4Relevant articles and documents
Catalytic reactivity of new Ni(II), Cu(II) and Sn(II) complexes for decolorization of indigo carmine in aqueous solution, high efficiency of copper complex
Nassar, Amr Mohammad
, (2018)
A new Ni(II), Cu(II) and Sn(II) Schiff base complexes were synthesized in this work. The characterization of the new complexes is carried out by elemental analysis, FT-IR, UV–Visible, 1H NMR and 13C NMR spectroscopy, conductance analysis, magnetic measurements and thermal gravimetric analysis. It was found that the ligand behaves as a dibasic bidentate which coordinated to the metal center through two deprotonated hydroxyl groups to form tetrahedral complex with Ni(II) and octahedral complex with Cu(II). The ligand acts as neutral bidentate through azomethine nitrogen and thiazol sulfur to form octahedral complex with Sn(II). The synthesized complexes are evaluated as catalysts for oxidative degradation of indigo carmine dye using H2O2 as oxidant and the efficiency of the catalysts is determined. The copper complex shows the best catalytic action with efficiency 92.17% after 25?min.
CTAB-assisted ultrasonic synthesis, characterization and photocatalytic properties of WO3
Sánchez-Martíneza, Daniel,Gómez-Solísa,Torres-Martíneza, Leticia M.
, p. 165 - 172 (2015)
WO32D nanostructures have been prepared by ultrasound synthesis method assisted with CTAB using different molar ratios. The formation of monoclinic crystal structure of WO3was confirmed by X-ray powder diffraction (XRD). The characterization of the WO3samples was complemented by analysis of scanning electron microscopy (SEM), which revealed morphology mainly of rectangular nanoplates with a thickness of around 50 nm and length of 100-500 nm. Infrared spectroscopy (FT-IR) was used to confirm the elimination of the CTAB in the synthesized samples. The specific surface area was determinate by the BET method and by means of diffuse reflectance spectroscopy (DRS) it was determinate the band-gap energy (Eg) of the WO3samples. The photocatalytic activity of the WO3oxide was evaluated in the degradation reactions of rhodamine B (rhB) and indigo carmine (IC) under Xenon lamp irradiation. The highest photocatalytic activity was observed in the samples containing low concentration of CTAB with morphology of rectangular nanoplates and with higher surface area value than commercial WO3. Photodegradation of rhB and IC were followed by means of UV-vis absorption spectra. The mineralization degree of organic dyes by WO3photocatalyst was determined by total organic carbon analysis (TOC) reaching percentages of mineralization of 92% for rhB and 50% for IC after 96 h of lamp irradiation.
Highly sensitive and selective bioluminescence based ozone probes and their applications to detect ambient ozone
Nam, Younseok,Kim, Beom Seok,Shin, Injae
supporting information, p. 1128 - 1130 (2016/01/15)
Highly selective and sensitive bioluminescence based probes, which respond to ozone but not to other ROS, have been developed. These probes were used to determine ozone concentrations in environmental samples.