73136-20-6

Basic information

• Product Name: (1aS,7bR)-1a,7b-dihydronaphtho[1,2-b]oxirene
• Synonyms: Naphth(1,2-b)oxirene, 1a,7b-dihydro-, (1aS,7bR)-
• CAS NO: 73136-20-6
• Molecular Formula: C₁₀H₈O
• Molecular Weight: 144.1699
• Mol File: 73136-20-6.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 264.1°C at 760 mmHg
• Flash Point: 109.4°C
• Density: 1.207g/cm³
• Vapor Pressure: 0.0162mmHg at 25°C
• Refractive Index: 1.626
• CAS DataBase Reference: (1aS,7bR)-1a,7b-dihydronaphtho[1,2-b]oxirene(CAS DataBase Reference)
• NIST Chemistry Reference: (1aS,7bR)-1a,7b-dihydronaphtho[1,2-b]oxirene(73136-20-6)
• EPA Substance Registry System: (1aS,7bR)-1a,7b-dihydronaphtho[1,2-b]oxirene(73136-20-6)

Safety Data

• Hazardous Substances Data: 73136-20-6(Hazardous Substances Data)

Upstream product

• 447-53-0 1,2-Dihydronaphthalene 
• 80522-73-2 (-)-(1R,2R)-trans-2-bromo-1-(2-methoxy-2-phenyl-2-trifluoromethylacetoxy)-1,2,3,4-tetrahydronaphthalene 
• 122874-28-6 (1R,2R)-trans-1-<<(+)-2-methoxy-2-phenyl-2-(trifluoromethyl)acetyl>oxy>-2-bromo-1,2,3,4-tetrahydronaphthalene 
• 39834-40-7 trans-2-bromo-1,2,3,4-tetrahydronaphthalen-1-ol 
• 1027954-16-0 Acetic acid (1S,2S)-4-bromo-1-chloro-1,2,3,4-tetrahydro-naphthalen-2-yl ester 
• 157982-38-2 Acetic acid (1S,2S)-1-chloro-1,2,3,4-tetrahydro-naphthalen-2-yl ester 
• 57495-92-8 (1R,2S)-1,2,3,4-tetrahydronaphthalene-1,2-diol 
• 51268-88-3 (1R,2S)-1,2-dihydronaphthalene-1,2-diol 
• 2461-34-9 (1R,2S)-1,2-epoxy-3,4-dihydronaphthalene 
• 122874-29-7 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2R)-2,4-dibromo-1,2,3,4-tetrahydro-naphthalen-1-yl ester 
• 122874-29-7 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2R)-2,4-dibromo-1,2,3,4-tetrahydro-naphthalen-1-yl ester 
• 122874-27-5 (1S,2S)-trans-1-<<(+)-2-methoxy-2-phenyl-2-(trifluoromethyl)acetyl>oxy>-2-bromo-1,2,3,4-tetrahydronaphthalene 
• 80522-79-8 (+)-(1S,2S)-trans-2-bromo-1-(2-methoxy-2-phenyl-2-trifluoromethylacetoxy)-1,2,3,4-tetrahydronaphthalene 
• 157982-44-0 (1R,2S)-1,2-dimesyloxy-1,2,3,4-tetrahydronaphthalene 

Downstream Products

• 135-88-6 N-Phenyl-2-naphthylamine 
• 2436-85-3 2-N,N-Dimethylaminonaphthalene 
• 7570-96-9 2-naphthyl phenyl sulfide 
• 7570-98-1 1-naphthyl phenyl sulfide 
• 90-15-3 α-naphthol 
• 135-19-3 β-naphthol 
• 54226-01-6 trans-1-hydroxy-2-methyl-1,2-dihydronaphthalene 

Relevant articles and documents

Enantioselective manganese-porphyrin-catalyzed epoxidation and C-H hydroxylation with hydrogen peroxide in water/methanol solutions

The asymmetric epoxidation of alkene and hydroxylation of arylalkane derivatives by H2O2 to give optically active epoxides (enantiomeric excess (ee) up to 68%) and alcohols (ee up to 57%), respectively, were carried out in water/methanol solutions using chiral water-soluble manganese porphyrins as catalysts.

A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation

In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.

Catalase and epoxidation activity of manganese salen complexes bearing two xanthene scaffolds

A series of manganese Hangman salen ligand platforms functionalized by tert-butyl groups in the 3 and 3′ positions using the Suzuki cross-coupling methodology are presented. The Hangman platforms support multielectron chemistry mediated by proton-coupled