7315-79-9Relevant academic research and scientific papers
Chelate-assisted oxidative coupling reaction of arylamides and unactivated alkenes: Mechanistic evidence for vinyl C-H bond activation promoted by an electrophilic ruthenium hydride catalyst
Kwon, Ki-Hyeok,Lee, Do W.,Yi, Chae S.
scheme or table, p. 5748 - 5750 (2011/02/23)
The cationic ruthenium hydride complex [(η6-C 6H6)(PCy3)(CO)RuH]+BF 4- was found to be a highly regioselective catalyst for the oxidative C-H coupling reaction of aryl-substituted amides and unactivated alkenes to give o-alkenylamide products. The kinetic and spectroscopic analyses support a mechanism involving a rapid vinyl C-H activation followed by a rate-limiting C-C bond formation step.
