73177-98-7Relevant academic research and scientific papers
One-pot synthesis of diaryliodonium salts using toluenesulfonic acid: A fast entry to electron-rich diaryliodonium tosylates and triflates
Zhu, Mingzhao,Jalalian, Nazli,Olofsson, Berit
, p. 592 - 596 (2008/12/22)
A direct synthesis of symmetric and unsymmetric electron-rich diaryliodonium salts is described. The use of MCPBA and toluenesulfonic acid delivers diaryliodonium tosylates in high yields. An in situ anion exchange has also been developed, giving access to the corresponding triflate salts. Georg Thieme Verlag Stuttgart.
New Methodology in Iodonium Salt Synthesis. Reactions of arenes with Aryltrimethylsilanes
Koser, Gerald F.,Wettach, Richard H.,Smith, Carol S.
, p. 1543 - 1544 (2007/10/02)
arenes react with aryltrimethylsilanes in acetonitrile to give diaryliodonium tosylates.The phenyliodinations proceed with silicon-carbon bond cleavage, thus allowing control of substituent placement in both rings.With bis(trimethyl
