73193-35-8Relevant academic research and scientific papers
Thermal Rearrangement of 1-(Carbomethoxy)-6-exo-(1-alkenyl)bicyclohex-2-ene Systems. A Convenient Synthesis of Functionalized Bicycloocta-2,6-dienes
Piers, Edward,Ruediger, Edward H.
, p. 1725 - 1727 (1980)
Thermal rearrangement of the substituted bicyclohex-2-enes 22-25 affords, in quantitative yields, the corresponding bicycloocta-2,6-dienes 26-29, respectively.On the other hand, thermolysis of 1-(carbomethoxy)-6-exo-vinylbicyclohex-3-
Synthesis of functionalized bicycloocta-2,6-dienes by thermal rearrangement of substituted 6-exo-(1-alkenyl)bicyclohex-2-ene systems
Piers, Edward,Jung, Grace L.,Ruediger, Edward H.
, p. 670 - 682 (2007/10/02)
Thermolysis of each of the enol silyl ethers 31-35 affords, cleanly and efficiently, the bicyclooctadienes 36-40, respectively.Similarly, thermal rearrangement of the enol silyl ether 50 provides the diene 51.Hydrolysis of 36, 37, and 39, and decar
