Thermal Rearrangement of 1-(Carbomethoxy)-6-exo-(1-alkenyl)bicyclohex-2-ene Systems. A Convenient Synthesis of Functionalized Bicycloocta-2,6-dienes

DOI: 10.1021/jo01297a056

Source and publish data:

Journal of Organic Chemistry p. 1725 - 1727 (1980)

Update date:2022-08-03

Topics:

Authors:

Piers, Edward

Ruediger, Edward H.

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Article abstract of DOI:10.1021/jo01297a056

Thermal rearrangement of the substituted bicyclo<3.1.0>hex-2-enes 22-25 affords, in quantitative yields, the corresponding bicyclo<3.2.1>octa-2,6-dienes 26-29, respectively.On the other hand, thermolysis of 1-(carbomethoxy)-6-exo-vinylbicyclo<3.1.0>hex-3-

Full text of DOI:10.1021/jo01297a056

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