733035-88-6Relevant articles and documents
Quantitative dynamic interconversion between AgI-mediated capsule and cage complexes accompanying guest encapsulation/release
Hiraoka, Shuichi,Harano, Koji,Shiro, Motoo,Shionoya, Mitsuhiko
, p. 2727 - 2731 (2005)
(Chemical Equation Presented) An accommodating host: Capsule- and cage-shaped complexes are formed from AgI and disk-shaped trismonodentate ligands in 1:1 and 1.5:1 concentration ratios, respectively; their interconversion is reversible. The ca
Using Anilines as Masked Cross-Coupling Partners: Design of a Telescoped Three-Step Flow Diazotization, Iododediazotization, Cross-Coupling Process
Teci, Matthieu,Tilley, Michael,McGuire, Michael A.,Organ, Michael G.
, p. 17407 - 17415 (2016/11/23)
The conversion of commercially available anilines into biaryl and biarylacetylene products was realized by using a telescoped, three-reactor flow diazotization/iododediazotization/cross-coupling process. The segmented flow stream created by off-gassing during the Sandmeyer sequence was restored to a continuous column of reaction solution by using a specially designed continuous-flow unit controlled by custom software created in-house. The resultant aryl iodide was then combined with a stream of cross-coupling solution that fed into the final reactor. The system proved versatile as modifications to the diazotization/iododediazotization sequence could be made rapidly to account for any substrate specificity (e.g., solubility problems), leading to a wide substrate scope of Suzuki–Miyaura and Sonogashira cross-coupled products.
Rh-catalyzed decarbonylation of conjugated ynones via carbon-alkyne bond activation: Reaction scope and mechanistic exploration via DFT calculations
Dermenci, Alpay,Whittaker, Rachel E.,Gao, Yang,Cruz, Faben A.,Yu, Zhi-Xiang,Dong, Guangbin
, p. 3201 - 3210 (2015/06/17)
In this full article, detailed development of a catalytic decarbonylation of conjugated monoynones to synthesize disubstituted alkynes is described. The reaction scope and limitation has been thoroughly investigated, and a broad range of functional groups