73312-68-2Relevant academic research and scientific papers
Formation of Pyrimidine-5-carboxaldehydes, 1-Aminoethylene-2,2-dicarboxaldehyde and 2-Amino-4-anilino-1,3,5-triazine from Triformylmethane and Amidines
Takagi, Kaname,Bajnati, Abdelilah,Hubert-Habart, Michel
, p. 973 - 976 (2007/10/02)
Triformylmethane (1) reacted with benzamidine, guanidine and S-methylisothiourea to give the corresponding 2-substituted pyrimidines-5-carboxaldehydes.However reactions of 1 with acetamidine (or formamidine) and phenylbiguanide gave the unexpected 1-aminoethylene-2,2-dicarboxaldehyde (5) and 2-amino-4-anilino-1,3,5-triazine (9), respectively.
