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Carbon-Carbon Bond-Formation via Ring-Opening between Cyclopropanes and Alkenes
Giese, Bernd,Zwick, Wolfgang
, p. 2526 - 2532 (2007/10/02)
Cyclopropanes 6 - 12 and alkenes 13 yield via methoxymercuration and reduction the products 14 - 20.The carbon-carbon bond-formation occurs under mild conditions because alkyl radicals 3 and 4 are intermediates in this synthesis.With electron-withdrawing substituents at alkenes 13 yields of 87 percent are reached (table 1).In these reactions mono- to tetrasubstituted cyclopropanes 6 - 12 can be used (table 2).
