73357-78-5

Basic information

• Product Name: Benzene, 1-(bromomethyl)-2-ethenyl-
• CAS NO: 73357-78-5
• Molecular Formula: C9H9Br
• Molecular Weight: 197.074
• Mol File: 73357-78-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(bromomethyl)-2-ethenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(bromomethyl)-2-ethenyl-(73357-78-5)
• EPA Substance Registry System: Benzene, 1-(bromomethyl)-2-ethenyl-(73357-78-5)

Safety Data

• Hazardous Substances Data: 73357-78-5(Hazardous Substances Data)

Upstream product

• 28272-96-0 2-vinylbenzaldehyde 
• 50-00-0 formaldehyd 
• 91-13-4 α,α'-dibromo-o-xylene 
• 122444-35-3 2-(2-bromomethyl)-phenethyl alcohol 
• 38256-56-3 1-(2-bromo-ethyl)-2-bromomethyl-benzene 
• 493-05-0 isochromane 
• 27326-43-8 2-vinylbenzoic acid 
• 506-68-3 bromocyane 
• 35106-82-2 2-vinylbenzylalcohol 

Downstream Products

• 138970-65-7 2-<(2-ethenylphenyl)methyl>cyclohexanone 
• 1319203-97-8 C₁₇H₁₈O₂ 
• 1319203-99-0 C₂₃H₃₂O₂Si 

Relevant articles and documents

Enantioselective Copper-Catalyzed Desymmetrization of 1,3-Diketones Involving Borylation of Styrenes

A copper-catalyzed intramolecular enantioselective and diastereoselective borylative coupling of styrenes and ketones was achieved by merging desymmetrization strategy and olefin difunctionalization. The reaction proceeds through an initial enantioselective borylcupration of styrenes, followed by a highly selective direct addition to 1,3-diketones. The bicyclic scaffolds with three chiral carbon centers, including two tetrasubstituted carbons, were generated in excellent yields, diastereoselectivities, and enantioselectivities. This catalytic tandem reaction has great potential for further synthetic application of the chiral polycyclic compounds, because of the versatility of the functional groups in the products.

NEW MACROCYCLIC AMIDINOUREA DERIVATIVES, METHODS OF PREPARATION AND USES THEREOF AS CHITINASE INHIBITORS

The present invention relates to macrocyclic amidinourea derivatives of formula 8, methods of preparation and uses thereof, pharmaceutical compositions in particular to be used as chitinase inhibitors in the treatment of a fungal infection.

A rapid and convergent synthesis of the integrastatin core

The tetracyclic core of the integrastatin natural products has been prepared in a convergent and rapid manner. Our strategy relies upon a palladium(ii)-catalyzed oxidative cyclization to form the central [3.3.1]-dioxabicycle of the natural product core. Overall, the core has been completed in only 4 linear steps from known compounds.