733800-70-9Relevant academic research and scientific papers
Direct asymmetric aldol-Tishchenko reaction of aliphatic ketones catalyzed by syn-aminoalcohol-Yb(III) complexes
Mlynarski, Jacek,Jankowska, Joanna,Rakiel, Bartosz
, p. 4854 - 4856 (2005)
The asymmetric direct aldol condensation of aldehydes with ethyl- and propylketones is catalyzed by syn-α-aminoalcohol-Yb(OTf)3 complexes, yielding the anti-1,3-diol monoesters with high diastereocontrol and good enantioselectivity. Three adjac
Dynamic structural change of the self-assembled lanthanum complex induced by lithium triflate for direct catalytic asymmetric aldol-Tishchenko reaction
Horiuchi, Yoshihiro,Gnanadesikan, Vijay,Ohshima, Takashi,Masu, Hyuma,Katagiri, Kosuke,Sei, Yoshihisa,Yamaguchi, Kentaro,Shibasaki, Masakatsu
, p. 5195 - 5204 (2007/10/03)
The development of a direct catalytic asymmetric aldol-Tishchenko reaction and the nature of its catalyst are described. An aldol-Tishchenko reaction of various propiophenone derivatives with aromatic aldehydes was promoted by [LaLi3(binol)sub
Direct catalytic asymmetric aldol-Tishchenko reaction
Gnanadesikan, Vijay,Horiuchi, Yoshihiro,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 7782 - 7783 (2007/10/03)
A direct catalytic asymmetric aldol reaction of propionate equivalent was achieved via the aldol-Tishchenko reaction. Coupling an irreversible Tishchenko reaction to a reversible aldol reaction overcame the retro-aldol reaction problem and thereby afforde
