7351-26-0Relevant articles and documents
A practical synthesis of cycloalkylphosphonates from trichloromethylphosphonates
Grandin,Collignon,Savignac
, p. 239 - 241 (1995)
Cycloalkylphosphonates 5 with ring size varying from 4 to 6 were synthesized in good overall yields, in two steps from trichloromethylphosphonates and ω-dibromoalkanes, via the corresponding α-trimethylsilyl cycloalkylphosphonates 4.
Facile solid-phase synthesis of cycloalkylphosphonates and 1-cycloalkenylphosphonates using polymer-supported phenylsulfonylmethylphosphonates
Liu, Xiao-Ling,Sheng, Shou-Ri,Zhou, Wei,Wang, Qin-Ying,Zhang, Xiao-Lan,Gong, Bin
, p. 119 - 127 (2007/10/03)
A facile procedure for the solid-phase synthesis of cycloalkylphosphonates and 1-cycloalkenylphosphonates in good yields and high purities using polystyrene-supported phenylsulfonylmethylphosphonates with traceless sulfone linker strategy is described. Copyright Taylor & Francis Group, LLC.
Free-Radical Phosphorylation of Olefins Initiated by Anodic Oxidation
Romakhin,Kosachev,Zagumennov,Nikitin
, p. 227 - 234 (2007/10/03)
Electrochemical oxidation of lithium and sodium dialkyl phosphites generates dialkyl phosphonyl radicals, which initiate chain free-radical addition of dialkyl phosphites across the alkene multiple bond to form alkyl(cycloalkyl)phosphonates. Alkyl(cycloalkyl)phosphonates are formed simultaneously owing to anodic oxidation of adsorbed primary radical adducts of phosphonyl radical and alkene molecule to give the carbenium cation, followed by deprotonation of the latter.