73551-02-7Relevant articles and documents
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Rendell,R.W.,Wright,B.
, p. 2405 - 2411 (1979)
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Electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine
Sartori,Velayutham,Ignat'ev,Noel
, p. 1 - 8 (2007/10/03)
The electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine was canied out in a modified Simons type cell using anhydrous hydrogen fluoride as a solvent. Effects of various experimental parameters like concentration of amine, temperature, and current density etc. were investigated. In addition to perfluoro-N,N,N',N'-tetramethylethylenediamine, cyclic, cleavage, and partially fluorinated products were obtained and characterized by gas chromatography, IR spectroscopy, nuclear magnetic resonance and mass spectra. A plausible reaction pathway for the electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine has been proposed based on the products obtained. Elsevier Science S.A.