73564-11-1

Basic information

• Product Name: (2,5-bis((trimethylsilyl)oxy)-1,4-phenylene)bis(trimethylsilane)
• Synonyms: (2,5-bis((trimethylsilyl)oxy)-1,4-phenylene)bis(trimethylsilane)
• CAS NO: 73564-11-1
• Molecular Weight: 398.841
• Mol File: 73564-11-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2,5-bis((trimethylsilyl)oxy)-1,4-phenylene)bis(trimethylsilane)(CAS DataBase Reference)
• NIST Chemistry Reference: (2,5-bis((trimethylsilyl)oxy)-1,4-phenylene)bis(trimethylsilane)(73564-11-1)
• EPA Substance Registry System: (2,5-bis((trimethylsilyl)oxy)-1,4-phenylene)bis(trimethylsilane)(73564-11-1)

Safety Data

• Hazardous Substances Data: 73564-11-1(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 97088-22-7 ((2,5-dibromo-1,4-phenylene)bis(oxy))bis(trimethylsilane) 
• 123-31-9 hydroquinone 
• 14753-51-6 2,5-dibromohydroquinone 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 18804-57-4 2,5-bis(trimethylsilyl)-1,4-benzoquinone 
• 101907-54-4 2,5-bis(trimethylsilyl)benzene-1,4-diol 

Relevant articles and documents

Preparation of bis-Benzyne Precursor 2,5-bis(Trimethylsilyl)-1,4-Phenylene bis(Trifluoromethanesulfonate)

-

Interactions in crystals. 76. Single crystal structures of 2,5-bis(trimethylsilyl)-hydroquinone without solvent and with either dimethoxyethane or dioxane: Some insight into the manifold of hydrogen bridge bonding of the same molecule

2,5-Bis(trimethylsilyl)hydroquinone (monoclinic, C2/c, Z=12) forms infinite strings in x-direction, in which alternatingly on both sides each three molecules are bound together by three phenolic H bridges in a triangular arrangement. In the dimethoxyethane solvate (triclinic, P1, Z=1) with a 3:2 ratio of phenol to ether, the infinite strings are interlinked by twice-OH...O bonded H3COCH2CH2OCH3 chelate molecules. The smallest subunit with only two Hydrogen bonds -OHO...(CH2CH2)O informed in the monomeric 2:1 dioxane solvate (triclinic, P1, Z=1), The structural details of the different H bridge bonds are discussed based both on a statistical analysis from the Cambridge Structural Database as well as on PM3-calculated enthalpies of formation starting from the crystal structures determined. Johann Ambrosius Barth 1996.