736140-63-9Relevant academic research and scientific papers
Asymmetric synthesis of (+)-1-epiaustraline and attempted synthesis of australine
Tang, Minyan,Pyne, Stephen G.
, p. 5759 - 5767 (2007/10/03)
A diastereoselective synthesis of the pyrrolizidine alkaloid, (+)-1-epiaustraline has been achieved via a diastereoselective syn-dihydroxylation of a pyrrolo[1,2-c]oxazol-3-one precursor that was readily prepared by a RCM reaction. Attempts to extend this
A study toward a total synthesis of fostriecin
Kiyotsuka, Yohei,Igarashi, Junji,Kobayashi, Yuichi
, p. 2725 - 2729 (2007/10/03)
In order to synthesize the major C(3)-C(12) part of fostriecin, asymmetric dihydroxylation of several dienes 5a-f, prepared by cross-coupling reactions of several types, was studied, thus providing high dependency on the hydroxyl groups at C(5) and C(11). The best regioselectivity was obtained with 5d to produce diol 23, which was later transformed into the advanced intermediate 26.
Stereoselective synthesis of [2S,3R]-β-hydroxy ornithine
Rao, B. Venkateswara,Krishna, U. Murali,Gurjar, Mukund K.
, p. 1335 - 1345 (2007/10/03)
(2S,3R)-threo-β-hydroxy ornithine has been synthesized in a stereoselective manner by the C2 opening of epoxyalcohol 9 with benzyl isocyanate.
