7367-38-6

Usage

InChI:InChI=1/C13H26/c1-4-7-10-13(11-8-5-2)12-9-6-3/h10H,4-9,11-12H2,1-3H3

Upstream product

• 100529-14-4 5-butyl-5-chlorononane 
• 597-93-3 tri-n-butyl-carbinol 
• 52061-79-7 2,2-dibutyl-hexanoyl chloride 
• 144-62-7 oxalic acid 
• 693-03-8 n-butyl magnesium bromide 
• 39141-54-3 2,2-bis(methylthio)-1,3-dithiane 
• 7553-56-2 iodine 
• 502-56-7 nonanone-5 
• 52061-76-4 2,2-dibutyl-hexanoic acid 
• 87437-01-2 Phosphoric acid (E)-1-butyl-pent-1-enyl ester diphenyl ester 

Downstream Products

• 502-56-7 nonanone-5 
• 123-72-8 butyraldehyde 

Relevant academic research and scientific papers

Iron-catalyzed alkenylation of Grignard reagents by enol phosphates

Stereoselective preparation of trisubstituted olefins can be easily performed from an Z/E-mixture of enol phosphates by reacting only the E-isomer with a Grignard reagent in the presence of Fe(acac)3. This procedure combines a kinetic differentiation and a stereoselective reaction. The coupling is very chemoselective in the presence of an alkyl chloride, an ester, a ketone or a nitrile. Georg Thieme Verlag Stuttgart.

Iodine induced transformations of alcohols under solvent-free conditions

Iodine has been shown to be an efficient catalyst for transformations of alcohols under solvent-free conditions. In the presence of 5% of iodine, tertiary alcohols underwent dehydration forming the corresponding alkenes, while in the case of 2-phenylpropane-2-ol cyclodimerisation to 1,1,3-trimethyl-3-phenylindane took place. Secondary and primary benzyl alcohols under the same conditions gave the corresponding ethers.

Trithioorthoesters and Tetrathioorthocarbonates as RC(3+) and C(4+) Synthons. Nickel-Catalyzed Alkylative Olefination of Trithioorthoesters and Tetrathioorthocarbonates

NiCl2(PPh3)2-catalyzed alkylative olefinations of trithioorthoesters and tetrathioorthocarbonates give the corresponding substituted alkenes.Aliphatic C-S bonds in these substrates can be activated in the nickel-catalyzed cross coupling reaction leading to carbon-carbon bond formation.This reaction can be considered as using trithiorthoesters and tetrathioorthocarbonate as R3C(3+) and C(4+) synthons. - Keywords: Trithioorthoesters, Tetrathioorthocarbonate, Nickel-Catalyzed Alkylative Olefination, Synthons of RC(3+) and C(4+)