73679-97-7Relevant academic research and scientific papers
Reactions involving fluoride ion. Part 42. Heterocyclic compounds from perfluoro-3,4-dimethylhexa-2,4-diene
Chambers, Richard D.,Gray, William K.,Mullins, Steven J.,Korn, Stewart R.
, p. 1457 - 1463 (2007/10/03)
Reactions of perfluoro-3,4-dimethylhexa-2,4-diene 1 with primary aromatic amines give both pyrrole 2 and pyrroloquinoline 3 derivatives, whilst ammonia gives dienes 10 and 12 as well as the novel pyrrole derivative 11. Catechol leads to a benzodioxocine s
A Synthesis of Novel Perfluorodienes
Briscoe, Mark W.,Chambers, Richard D.,Mullins, Steven J.,Nakamura, Takayuki,Drakesmith, Frederick G.
, p. 1127 - 1128 (2007/10/02)
Oligomers of perfluoroalkenes are converted to dienes in good yields, using sodium amalgam; these dienes are highly susceptible to nucleophilic attack and can be excellent sources of heterocycles.
Organic Fluorine Compounds. 32. A 1,3-Dipolar Cycloaddition Reaction of Tetrakis(trifluoromethyl)(Dewar Thiophene) and Some Reactions of the Cycloadducts
Kobayashi, Yoshiro,Ando, Akira,Kawada, Kosuke,Ohsawa, Akio,Kumadaki, Itsumaro
, p. 2962 - 2966 (2007/10/02)
The reaction of tetrakis(trifluoromethyl)(Dewar thiophene) (1) with azide compounds 2, including hydrogen azide, gave high yields of 1,3-dipolar cycloadducts 3.Compounds 3a-d were desulfurized with triphenylphosphine to afford cyclobutatriazoline compound
Organic Fluorine Compounds. 34. Some Reactions of Valence-Bond Isomers of Tetrakis(trifluoromethyl)pyrroles
Kobayashi, Yoshiro,Ando, Akira,Kawada, Kosuke,Kumadaki, Itsumaro
, p. 2968 - 2970 (2007/10/02)
By use of the valence-bond isomers of trifluoromethylated pyrrole compounds, the mechanism of photochemical transformation of five-membered aromatic compounds was studied.The formerly postulated intermediates, Dewar pyrroles or cyclopropenyl imines, did n
