73683-78-0Relevant academic research and scientific papers
Regioselective ring opening of exo- and endo-3,4-benzylidene acetals of arabinopyranoside derivatives with Lewis acids and reducing agents
Rujirawanich, Janjira,Kongkathip, Boonsong,Kongkathip, Ngampong
experimental part, p. 927 - 932 (2011/06/20)
Dioxolane type 3,4-benzylidene acetals of benzyl β-l-arabinose either as a mixture or pure exo- and endo-isomers cleavaged with BF3· OEt2/Et3SiH in dichloromethane or acetonitrile regioselectively, provided the 4-O-benzyl-
STEREOSELECTIVE HYDROGENOLYSIS OF DIOXOLANE-TYPE BENZYLIDENE ACETALS; PREPARATION OF MONO- AND DI-O-BENZYL ETHERS OF BENZYL β-L-ARABINOPYRANOSIDE
Liptak, A.,Szurmai, Z.,Harangi, J.,Nanasi, P.
, p. 333 - 342 (2007/10/02)
Both isomers (2 and 3) of benzyl 3,4-O-benzylidene-β-L-arabinopyranoside, their 2-O-benzyl- (4 and 5), 2-O-allyl (6 and 7) and 2-O-p-toluenesulfonyl (8 and 9) derivatives were prepared and hydrogenolyzed with LiAlH4-AlCl3 reagent.The exo-isomers (2, 4, 6)
Branched-chain Sugars. XXII. Synthesis of Benzyl 2,3-Di-O-benzyl- and 2,3-O-Methylene-β-L-threo-pentopyranosid-4-uloses, and the Corresponding 6-Deoxy-α-D-xylo-hexopyranosid-4-uloses
Matsuzawa, Masafumi,Kubo, Kazusuke,Kodama, Hisashi
, p. 2169 - 2173 (2007/10/02)
The title compounds were synthesized from L-arabinose and D-glucose as intermediates to a few naturally occurring branched-chain sugars.Oxidation conditions of precursors to the corresponding 4-uloses were examined.
