73684-08-9

Upstream product

• 73684-07-8 methyl 2,3,4-trideoxy-2,4-C-dimethyl-α-D-lyxo-hexopyranoside 
• 98-59-9 p-toluenesulfonyl chloride 
• 51385-38-7 (2S,3R,6S)-6-(hydroxymethyl)-2-methoxy-3,6-dihydro-2H-pyran-3-ol 
• 80532-19-0 methyl 3,4-dideoxy-6-O-(1-ethoxyethyl)-α-D-glycero-hex-3-enopyranosid-2-ulose 
• 68880-95-5 methyl 2,3,4-trideoxy-2,4-di-C-methyl-6-O-(triphenylmethyl)-α-D-lyxo-hexopyranoside 
• 73656-98-1 methyl 2,3,4-trideoxy-4-C-methyl-2-C-methylene-6-O-(triphenylmethyl)-α-D-threo-hexopyranoside 
• 66149-56-2 methyl 3,4-dideoxy-4-C-methyl-6-O-(triphenylmethyl)-α-D-threo-hexopyranosid-2-ulose 
• 492-62-6 alpha-D-glucopyranose 
• 95015-43-3 methyl 3,4-dideoxy-6-O-(1-ethoxyethyl)-4-C-methyl-α-D-threo-hexopyranosid-2-ulose 
• 95015-36-4 methyl 2,3,4-trideoxy-6-O-(1-ethoxyethyl)-4-C-methyl-2-C-methylene-α-D-threo-hexopyranoside 

Downstream Products

• 82335-98-6 serricornin acetate <(4S,6R,7R)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 110561-04-1 13-O-benzoyl-1,3-O-cyclohexylidene-2,4,5,6,8,9,10,12-octadeoxy-11-O-(1-ethoxyethyl)-4,8,10,12-C-tetramethyl-D-gluco(and D-manno)-D-threo-7-trideculose trimethylene dithioacetal 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF ANTIBIOTIC A23187 (CALCIMYCIN) FROM D-GLUCOSE

The fully stereocontrolled synthesis A23187 by using the chirons derived from D-glucose is described.