73656-98-1

Upstream product

• 39598-55-5 (bromomethylene)triphenylphosphorane 
• 66149-56-2 methyl 3,4-dideoxy-4-C-methyl-6-O-(triphenylmethyl)-α-D-threo-hexopyranosid-2-ulose 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 19493-09-5 Methylenetriphenylphosphorane 
• 35303-94-7 (2S,6S)-2-Methoxy-6-trityloxymethyl-6H-pyran-3-one 
• 79607-38-8 (2S,5S,6S)-2-Methoxy-5-methyl-6-trityloxymethyl-dihydro-pyran-3-one 
• 79607-37-7 methyl 3,4-dideoxy-4-c-methyl-6-o-trityl-α-D-glycero-hex-3-enopyranosid-2-ulose 

Downstream Products

• 68880-95-5 methyl 2,3,4-trideoxy-2,4-di-C-methyl-6-O-(triphenylmethyl)-α-D-lyxo-hexopyranoside 
• 73679-58-0 methyl 2,3,4-trideoxy-2,4-di-C-methyl-6-O-(triphenylmethyl)-α-D-arabino-hexopyranoside 
• 79646-64-3 methyl 2,3,4-trideoxy-2,4-di-C-methyl-α-D-arabino-hexopyranoside 
• 79646-63-2 methyl 2,3,4-trideoxy-2,3-di-C-methyl-6-O-trityl-α-D-ribo-hexopyranoside 
• 80516-28-5 (2S,3R,5R)-1-Benzyloxy-3,5-dimethyl-oct-7-ene-2,6-diol 
• 73657-04-2 8-(benzyloxy)-4,6-dimethyl-3-oxo-1-octen-7-ol 
• 80516-19-4 methyl 6-O-benzyl-2,3,4-trideoxy-2,4-di-C-methyl-α-D-lyxo-hexopyranoside 
• 80516-26-3 6-O-benzyl-2,3,4-trideoxy-2,4-di-C-methyl-D-lyxo-hexopyranose 
• 59014-03-8 (-)-α-multistriatin 
• 110561-04-1 13-O-benzoyl-1,3-O-cyclohexylidene-2,4,5,6,8,9,10,12-octadeoxy-11-O-(1-ethoxyethyl)-4,8,10,12-C-tetramethyl-D-gluco(and D-manno)-D-threo-7-trideculose trimethylene dithioacetal 
• 73684-08-9 methyl 2,3,4-trideoxy-2,4-C-dimethyl-6-O-(p-toluenesulfonyl)-α-D-lyxo-hexopyranoside 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF ANTIBIOTIC A23187 (CALCIMYCIN) FROM D-GLUCOSE

The fully stereocontrolled synthesis A23187 by using the chirons derived from D-glucose is described.

Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 4. Synthesis of (-)-α-Multistriatin

The precursor for (-)-α-multistriatin (alkyl 2,3,4-trideoxy-2,4-di-C-methyl-α-D-lyxo-hexopyranoside) may be approached from the corresponding isomeric 4-oxo-2-C-methyl- or 2-oxo-4-C-methylpyranosides by (a) methylenation followed by (b) hydrogenation.The

A ROUTE TO PRELOG-DJERASSI LACTONE FROM METHYL α,D-GLUCOPYRANOSIDE

The enone 1 obtainable from methyl α,D-glucopyranoside is converted into the corresponding diene 5 which is hydrogenated to give predominantly the diequatorial dimethyl hexopyranoside 3.C6 of the latter is converted stepwise to the methyl ketone from whic