73706-62-4

Basic information

• Product Name: 1-tosyloxy-3,7-dimethyl-6-octene-2-one
• Synonyms: 1-tosyloxy-3,7-dimethyl-6-octene-2-one
• CAS NO: 73706-62-4
• Molecular Weight: 324.441
• Mol File: 73706-62-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-tosyloxy-3,7-dimethyl-6-octene-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-tosyloxy-3,7-dimethyl-6-octene-2-one(73706-62-4)
• EPA Substance Registry System: 1-tosyloxy-3,7-dimethyl-6-octene-2-one(73706-62-4)

Safety Data

• Hazardous Substances Data: 73706-62-4(Hazardous Substances Data)

Upstream product

• 2111-52-6 1-diaza-3,7-dimethyl-6-octene-2-one 
• 104-15-4 toluene-4-sulfonic acid 
• 73706-64-6 2,6-dimethyl-hept-5-enoyl chloride 
• 24555-30-4 2,6-dimethyl-5-heptenoic acid 
• 110-93-0 6-Methyl-hept-5-en-2-on 
• 4434-77-9 2-bromo-6-methylhept-5-ene 
• 4630-06-2 6-methylhept-5-en-2-ol 
• 54088-65-2 rac-2,6-dimethylhept-5-enenitrile 

Downstream Products

• 3792-53-8 2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 26728-44-9 ethyl rac-3,7-dimethyloct-6-enoate 
• 23733-68-8 p-menth-3-en-2-one 

Relevant articles and documents

Photoreactions of α-sulfonyloxyketones

Earlier work on the photochemistry of α-sulfonyloxyketones uncovered their propensity to form the corresponding α-ketocarbonium ions on photolysis.Typical reactions such as intramolecular cyclizations, carbonium ion rearrangements, and solvent trapping were found.This paper describes an attempt to extend this reaction to a general synthetic technique for polyene cyclizations.During the course of this work two other major reaction pathways were found.The first is an α-keto carbonium ion to acylium ion rearrangement and the second is a photoreduction-elimination process that leads to an α-keto radical rather than the corresponding cation.