73728-29-7Relevant academic research and scientific papers
Investigation of Ion-Molecular Reactions of Nucleogenic Phenyl Cations with 1,4-Diazine Derivatives
Shchepina,Avrorin,Badun,Vasyanin,Shurov,Agafonova
, p. 1595 - 1601 (2015)
The use of nuclear-chemical synthesis, based on the generation of free nucleogenic phenyl cations, allowed for the direct phenylation of the nitrogen atom in 1,4-diazines. The presence of two methyl substituents in the quinoxaline substrate leads to a mar
Preparation of N-phenyl-substituted quinolinium derivatives labeled with tritium by chemonuclear synthesis
Shchepina,Avrorin,Badun,Alexandrova,Ukhanov,Fedoseev,Lewis,Boiko
, p. 796 - 801 (2009)
A chemonuclear method of synthesis is proposed for obtaining difficultly available phenyl-substituted derivatives of quinoline labeled with tritium. The ion-molecule reaction of free phenyl cations, generated on β-decay of tritium, with the nucleophilic c
Preparation of n-phenylbenzo[h]quinolinium derivatives labeled with tritium
Shchepina,Avrorin,Badun,Boiko
, p. 1196 - 1199 (2012)
The possibility of a direct phenylation of benzoquinoline nitrogen atom with nucleogenic phenyl cations has been demonstrated. A simple method has been developed for obtaining previously unknown tritium labeled N-phenyl derivatives of benzo[h]quinolinium, which are promising radioactive markers for studying the biological action mechanisms of medicinal substances containing the benzoquinolinium structure.
