73732-53-3Relevant academic research and scientific papers
Strain-Promoted 1,3-Dithiolium-4-olates–Alkyne Cycloaddition
Kumar, Ramar Arun,Pattanayak, Manas R.,Yen-Pon, Expédite,Eliyan, Jijy,Porte, Karine,Bernard, Sabrina,Riomet, Margaux,Thuéry, Pierre,Audisio, Davide,Taran, Frédéric
supporting information, p. 14544 - 14548 (2019/09/17)
Reported here is the reactivity of mesoionic 1,3-dithiolium-4-olates towards strained alkynes, leading to thiophene cycloaddition products. In the process, the potential of these dipoles towards orthogonal reaction with azides, allowing efficient double ligation reactions, was discovered. A versatile process to access benzo[c]thiophenes, in an unprecedented divergent fashion, was developed and provides a new entry to unconventional polyaromatic thiophenes.
Narrow disperse polymers using amine functionalized dithiobenzoate RAFT agent and easy removal of thiocarbonyl end group from the resultant polymers
Jana, Satyasankar,Parthiban, Anbanandam,Chai, Christina L.L.
experimental part, p. 1494 - 1502 (2012/02/05)
A novel amine functionalized RAFT agent, 2-cyanoprop-2-yl(4-N,N- dimethylaminophenyl) dithiobenzoate has been synthesized and used to control the polymerization of vinyl monomers. This dithiobenzoate RAFT agent, although air sensitive, controlled the poly
