73807-73-5Relevant academic research and scientific papers
Stereoselective hydrogenations of aryl-substituted dienes
Cui, Xiuhua,Ogle, James W.,Burgess, Kevin
, p. 672 - 674 (2005)
The carbene complex 1 can mediate hydrogenations of dienes with up to 20:1.0 diastereoselectivity and 99% ee; the scope and limitations of these reactions were investigated. The Royal Society of Chemistry 2005.
Photochemical Addition of Benzyltriethylgermane and Dibenzyldiethylgermane to Olefines
Kobayashi, Masanori,Yoshida, Masato,Kobayashi, Michio
, p. 3169 - 3174 (2007/10/02)
A novel photochemical addition of a germanyl radical to the olefinic double bond was discovered when benzyltriethylgermane or dibenzyldiethylgermane was irradiated with a medium-pressure mercury lamp in the presence of olefins.
AN OLEFIN POLYANION EQUIVALENT: A NEW OLEFIN SYNTHESIS FROM TRIFLONES
Hendrickson, James B.,Boudreaux, Gerald J.,Palumbo, Paul S.
, p. 4617 - 4618 (2007/10/02)
α-Trifyl-dimethylsulfone (CF3SO2CH2SO2CH3) is a reagent which allows successive polyalkylation of the two carbons with regiocontrol.The polyalkylated trifyl-sulfone then undergoes a Ramberg-Baecklund reaction with loss of triflinate anion and extrusion of SO2 to form an olefin.In synthetic terms the net structural change is equivalent to regiospecific alkylation of an olefin polyanion, =C==C=.
