93916-02-0

Basic information

• Product Name: Benzene, [2-[(1-methyl-2-phenylethyl)sulfonyl]-2-[(trifluoromethyl)sulfonyl]propyl]-
• CAS NO: 93916-02-0
• Molecular Formula: C19H21F3O4S2
• Molecular Weight: 434.501
• Mol File: 93916-02-0.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [2-[(1-methyl-2-phenylethyl)sulfonyl]-2-[(trifluoromethyl)sulfonyl]propyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [2-[(1-methyl-2-phenylethyl)sulfonyl]-2-[(trifluoromethyl)sulfonyl]propyl]-(93916-02-0)
• EPA Substance Registry System: Benzene, [2-[(1-methyl-2-phenylethyl)sulfonyl]-2-[(trifluoromethyl)sulfonyl]propyl]-(93916-02-0)

Safety Data

• Hazardous Substances Data: 93916-02-0(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 93916-01-9 [2-(1-Trifluoromethanesulfonyl-ethanesulfonyl)-propyl]-benzene 
• 93915-93-6 α,α'-dimethylmesyltriflone 

Downstream Products

• 73807-73-5 (C₆H₅CH₂)C(CH₃)C(CH₃)(CH₂C₆H₅) 

Relevant articles and documents

Nuclear Synthons: Mesyltriflone as an Olefin Polyanion Equivalent

Mesyltriflone (CF3SO2CH2SO2CH3) is developed as a nuclear synthon reagent capable first of multiple constructions such as alkylations then of Ramberg-Baecklund elimination to a substituted olefin.The alkylations are clean and regiospecific, often amenable to one-pot operation, and in most cases the elimination is smooth.A variety of examples is presented to establish the scope of the method, and the mechanism and stereochemistry are discussed.

AN OLEFIN POLYANION EQUIVALENT: A NEW OLEFIN SYNTHESIS FROM TRIFLONES

α-Trifyl-dimethylsulfone (CF3SO2CH2SO2CH3) is a reagent which allows successive polyalkylation of the two carbons with regiocontrol.The polyalkylated trifyl-sulfone then undergoes a Ramberg-Baecklund reaction with loss of triflinate anion and extrusion of SO2 to form an olefin.In synthetic terms the net structural change is equivalent to regiospecific alkylation of an olefin polyanion, =C==C=.