73845-02-0Relevant articles and documents
One-Pot Synthesis of Diazirines and 15N2-Diazirines from Ketones, Aldehydes and Derivatives: Development and Mechanistic Insight
Ibert, Quentin,Cauwel, Madeleine,Glachet, Thomas,Tite, Tony,Le Nahenec-Martel, Patricia,Lohier, Jean-Fran?ois,Renard, Pierre-Yves,Franck, Xavier,Reboul, Vincent,Sabot, Cyrille
supporting information, p. 4390 - 4398 (2021/08/03)
Broad scope one-pot diazirine synthesis strategies have been developed using two different oxidants depending on the nature of the starting material. In all cases, an inexpensive commercial solution of ammonia (NH3) in methanol (MeOH) was emplo
Mild Darzens Annulations for the Assembly of Trifluoromethylthiolated (SCF3) Aziridine and Cyclopropane Structures
Delost, Michael D.,Njardarson, Jon T.
supporting information, p. 6121 - 6125 (2021/08/16)
We report mild new annulation approaches to trisubstituted trifluoromethylthiolated (SCF3) aziridines and cyclopropanes via Darzens inspired protocols. The products of these anionic annulations, rarely studied previously, possess attractive features rendering them valuable building blocks for synthesis platforms. In this study, trisubstituted acetophenone nucleophiles bearing SCF3 and bromine substituents in their α position were shown to undergo [2 + 1] annulations with vinyl ketones and tosyl-protected imines under mild reaction conditions.
Efficient preparation of sulfonylimines, imidazoles and bis (indolyl)methanes catalyzed by [Et 3NSO 3H]Cl
Zare, Abdolkarim,Bahrami, Firoozeh,Merajoddin, Maria,Bandari, Marzieh,Moosavi-Zare, Ahmad Reza,Zolfigol, Mohammad Ali,Hasaninejad, Alireza,Shekouhy, Mohsen,Beyzavi, Mohammad Hassan,Khakyzadeh, Vahid,Mokhlesi, Mohammad,Asgari, Zhila
, p. 211 - 219 (2013/07/11)
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