73918-01-1

Upstream product

• 100-34-5 benzene diazonium chloride 
• 106-99-0 buta-1,3-diene 
• 62-53-3 aniline 
• 22656-00-4 (±)-1-phenylbut-3-en-2-yl acetate 
• 6052-66-0 1-phenyl-3-buten-2-ol 

Downstream Products

• 17432-35-8 4-(p-Tolylseleno)-1-phenylbut-2-en 
• 17538-18-0 4-(p-Methoxyphenylseleno)-1-phenyl-2-buten 
• 935-00-2 trans-4-phenyl-2-butene 
• 32917-66-1 1,8-diphenyl-2,6-octadiene 
• 82720-00-1 Z-4-chloro-1-phenyl-2-butene 
• 1443129-06-3 tert-butyl (1S,2R,3R)-2-benzylbicyclo[1.1.0]butane-1-carboxylate 
• 1443129-44-9 C₁₈H₂₄O₃ 
• 1195971-82-4 C₁₀H₁₁Cl₃Si 
• 612-17-9 1,4-dihydronaphthalene 
• 3029-40-1 diphenyloctatetraene 
• 17432-65-4 4-(p-Chlorphenylseleno)-1-phenylbut-2-en 

Relevant academic research and scientific papers

Acetyl chloride-ethanol brings about a remarkably efficient conversion of allyl acetates into allyl chlorides

AcCl-EtOH transforms primary and secondary allyl acetates into allyl chlorides that retain the olefinic bond in the more stable position. Whereas secondary allyl alcohols also react with almost the same efficacy as the acetates, the reactions of primary allyl alcohols that possess 1, 2-disubstituted alkenes are very slow. The products are isolated in high state of purity simply by removal of the volatiles.

1,8-napthalenedicarboximides as antidotes

Substituted 1,8-naphthalenedicarboximides of the formula: STR1 wherein R1, R2, R3, R4, R5, R6, X, Y, and Z have the meanings recited in the disclosure are disclosed as new compounds suitabl

REACTION OF 1,3-ALKADIENES WITH ARENEDIAZONIUM CHLORIDES IN THE PRESENCE OF IRON(II) CHLORIDE

The reaction of arenediazonium chlorides with 1,3-alkadienes in the presence of iron(II) chloride was investigated.It was established that the reaction takes place with the formation of products from chloroarylation of the dienes, telomerization, and additive dimerization.A method is proposed for the synthesis of diaryloctatetraenes containing substituents in the aromatic rings and in the aliphatic chain.