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N,N'-bis(2-hydroxy-3-Methoxy-benzylidene)ethylenediamine, also known as 2,2'-[(2-hydroxy-3-methoxy-5-methyl-1,3-phenylene)bis(azanylylidene)]bis-ethan-1-ol, is a complex organic compound with the molecular formula C18H22N2O4. It is a derivative of ethylenediamine, featuring two benzylidene groups attached to the nitrogen atoms, which are further substituted with hydroxy and methoxy groups. N,N'-bis(2-hydroxy-3-Methoxy-benzylidene)ethylenediaMine is known for its potential applications in various fields, including pharmaceuticals and materials science, due to its unique chemical structure and properties. It is often synthesized through condensation reactions and can be used as a building block for more complex molecules or as a ligand in coordination chemistry.

7396-77-2

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7396-77-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7396-77-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,9 and 6 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 7396-77:
(6*7)+(5*3)+(4*9)+(3*6)+(2*7)+(1*7)=132
132 % 10 = 2
So 7396-77-2 is a valid CAS Registry Number.

7396-77-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N'-(1,2-ethylene)-bis(3-methoxysalicylideneimine)

1.2 Other means of identification

Product number -
Other names N,N'-bis(2-hydroxyl-3-methoxybenzylidene)ethylenediamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7396-77-2 SDS

7396-77-2Relevant academic research and scientific papers

Formation of polynuclear copper(II)-sodium(I) heterometallic complexes derived from salen-type Schiff bases

Bhowmik, Prasanta,Harms, Klaus,Chattopadhyay, Shouvik

, p. 113 - 120 (2013)

Three heteronuclear Cu(II)/Na(I) complexes, [Cu2(salen) 2Na(ClO4)(CH3CN)] (1) [Cu2(vanen) 2Na2(μ1,1-NCS)2] (2) and [(Cu)2(L)2(Na)

Threading Salen-type Cu- and Ni-Complexes into One-Dimensional Coordination Polymers: Solution versus Solid State and the Size Effect of the Alkali Metal Ion

Finelli, Alba,Hérault, Nelly,Crochet, Aurélien,Fromm, Katharina M.

, p. 1215 - 1226 (2018)

Compartmentalization of metal ions is crucial in biology as well as in materials science. For the synthesis of single source precursors, the preorganization of different metal ions is of particular interest for the low-temperature generation of mixed meta

Selective targeting of synthetic antioxidants to mitochondria: Towards a mitochondrial medicine for neurodegenerative diseases?

Dessolin, Jean,Schuler, Marie,Quinart, Alice,De Giorgi, Francesca,Ghosez, Leon,Ichas, Fran?ois

, p. 155 - 161 (2002)

Mitochondria are the major source of superoxide, and are responsible for activating apoptosis and oxidative damage during acute neuronal cell death and neurodegenerative disorders like Alzheimer and Parkinson diseases. While the molecular mechanisms by wh

Homogeneous and heterogeneous styrene epoxidation catalyzed by copper(II) and nickel(II) Schiff base complexes

Liu, Deng-Feng,Lue, Xing-Qiang,Lu, Rong

, p. 705 - 712 (2014)

Both monomeric Schiff base complexes and 1D helical polymeric complexes of Cu(II) and Ni(II) were synthesized and characterized by physicochemical and spectroscopic methods. X-ray single-crystal studies were made on [K 2(CuL)2Ni(CN)

Controllable bulk solvent-free melt ring-opening polymerization (ROP) of l-lactide catalyzed by Ni(II) and Ni(II)-Ln(III) complexes based on the Salen-type Schiff-base ligand

Jin, Wen-Juan,Ding, Li-Qin,Chu, Zeng,Chen, Lei-Lei,Lü, Xing-Qiang,Zheng, Xiao-Yan,Song, Ji-Rong,Fan, Dai-Di

, p. 25 - 32 (2011)

A monometallic (Ni2+, 1) and a series of bimetallic (Ni 2+-Ln3+, Ln = Ce (2); Ln = Nd (3); Ln = Sm (4); Ln = Eu (5); Ln = Tb (6); Ln = Ho (7); Ln = Tm (8)) complexes based on the Salen-type Schiff-base ligand H2

Tetranuclear NIR luminescent Schiff-base Zn-Nd complexes

Lue, Xingqiang,Bi, Weiyu,Chai, Wenli,Song, Jirong,Meng, Jianxin,Wong, Wai-Yeung,Wong, Wai-Kwok,Jones, Richard A.

, p. 127 - 131 (2008)

With the simple dinuclear Zn-Nd complex [ZnNdL(H2O)(NO 3)3] (1) (H2L = N,N′-bis(3- methoxysalicylidene)ethylene-1,2-diamine) as the precursor, tetranuclear [Zn2Nd2L2(4,4′-bpy)(NO3) 6]·Et2O (2) and [Zn2Nd2L 2(4,4′-bpe)]·2H2O (3) (4,4′-bpy = 4,4′-bipyridine, 4,4′-bpe = trans-bis(4-pyridyl)ethylene) complexes are formed: suitable choice of bidentate linkers could construct multinuclear heterometallic 3d-4f Schiff-base complexes with improved luminescent properties, and the controlling of linker character shows a potentially effective way to the fine-tuning properties of NIR luminescence from Nd ions. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

On new solvatomorphs of the metalloligand [Ni(o-van-en)]

?ernák, Juraj,Falvello, Larry R.,Titi?, Ján,Tomás, Milagros,Vráblová, Anna

, (2020)

The Schiff-base bis-(2-hydroxy-3-methoxybenzylidene)ethylenediamine, denoted H2(o-van-en), is a versatile two-compartment polydentate ligand that can bring different guests, such as a transition metal and a lanthanoid, into close proximity to p

A new versatile class of hetero-tetra-metallic assemblies: Highlighting single-molecule magnet behaviour

Bridonneau, Nathalie,Chamoreau, Lise-Marie,Laine, Philippe P.,Wernsdorfer, Wolfgang,Marvaud, Valerie

, p. 9476 - 9478 (2013)

Hetero-tetra-metallic species based on hexanuclear assemblies [((valen)M1)Ln(OH2)2(μM2(CN)8)] 22- (Ln = GdIII, TbIII; M1 = Cu II, NiII and M2 = MoIV/s

Bulk solvent-free melt ring-opening polymerization of L-lactide catalyzed by Cu(II) and Cu(II)-Nd(III) complexes of the Salen-type Schiff-base ligand

Chen, Lei-Lei,Ding, Li-Qin,Zeng, Chu,Long, Yong,Lue, Xing-Qiang,Song, Ji-Rong,Fan, Dai-Di,Jin, Wen-Juan

, p. 310 - 316 (2011)

A monometallic (Cu2+, 1) and a bimetallic (Cu 2+-Nd3+, 2) Salen-type Schiff-base complexes with different reactive species, could efficiently catalyze the bulk solvent-free melt ring-opening polymerization (ROP) of L-lacti

The standard molar enthalpy of formation of a new copper(II) Schiff-base complex and its interaction with bovine serum albumin

Xie, Jin-Qi,Li, Chuan-Hua,Dong, Jia-Xin,Qu, Wei,Pan, Lan,Peng, Meng-La,Xie, Ming-An,Tao, Xu,Yu, Cheng-Mao,Zhu, Yi,Zhang, Ping-Hua,Tang, Chun-Guang,Li, Qiang-Guo

, p. 7 - 15 (2014)

A new copper(II) Schiff-base complex [Cu(HL)·NO3·MeOH] was prepared by using equivalent molar of Valen Schiff-base ligand [H2LN,N′-ethylene-bis(3-methoxysalicylideneimine)] and Cu(NO3)2·3H2O. The stru

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