74032-91-0Relevant articles and documents
Synthesis of aryl α-O-L-rhamnopyranoside by two-step reaction in one pot
Liu, Nianping,Tian, Xiangguang,Ding, Zekun,Zhou, Yongda,Zhang, Wan,Wang, Qingbing,Zhang, Yi,Gu, Yijun,Zhang, Jianbo
, p. 220 - 234 (2017/11/10)
The title compounds were conveniently synthesized by a phase transfer catalyzed approach in two steps and one pot using the rhamnopyranosyl chloride as key intermediate. The twostep one-pot procedure is more convenient and environmentally friendly, compared to the published synthetic routes. Besides, the structure-reactivity relationship and the plausible mechanism for this base-catalyzed glycosylation were discussed bymeans of the Hammett equation.