74045-16-2Relevant academic research and scientific papers
Reactions at Silicon Centres bearing the Bulky Tris(phenyldimethylsilyl)methyl Ligand
Eaborn, Colin,Mansour, Abdulrahman I.
, p. 729 - 736 (2007/10/02)
Metallation of (PhMe2Si)3CH with MeLi in tetrahydrofuran gives (PhMe2Si)3CLi, which reacts with MeI to give (PhMe2Si)3CMe, and also with Me2SiHCl and MeSiHCl2, to give (PhMe2Si)3CSiMe2H and (PhMe2Si)3CSiMe(H)Cl, respectively, but not with Me3SiCl or a ran
Reaktivitaet des Silaethens Me2Si=C(SiMe3)2: Thermolyse von (Me3Si)2(Me2XSi)CLi (X z. B. (PhO)2PO2) in Anwesenheit von Silaethen-Faengern
Wiberg, Nils,Preiner, Gerhard,Schieda, Oswald
, p. 3518 - 3532 (2007/10/02)
Silaethene Me2Si=C(SiMe3)2 (1), generated as a reaction intermediate by the thermal elimination of LiX from Me2XSi-CLi(SiMe3)2, combines with the reactants a - b (e. g.Me3Si-Cl, Me3Si-OMe) with insertion in the a - b bond, with a = b - c - H (e. g.CH2=CMe
