74069-32-2Relevant academic research and scientific papers
CYCLODEXTRIN-CATALYZED HYDROLYSIS OF ESTERS BEARING A HYDROPHOBIC TAIL
Ueno, Akihiko,Suzuki, Iwao,Hino, Yoshihiro,Suzuki, Atsuko,Osa, Tetsuo
, p. 159 - 162 (1985)
γ-Cyclodextrin-catalyzed hydrolysis of p-nitrophenyl esters bearing a long alkyl chain proceeded with larger rate acceleration than those with a short alkyl chain.Such rate acceleration behavior was not observed with β-cyclodextrin.The results suggest that the esters with a long alkyl chain take a folded structure (Type A) in the γ-cyclodextrin cavity.
HYDROLYTIC CLEAVAGE OF p-NITROPHENYL ALKANOATES IN AQUEOUS SOLUTIONS OF CYCLODEXTRINS
Bonora, Gian Maria,Fornasier, Roberto,Scrimin, Paolo,Tonellato, Umberto
, p. 367 - 370 (2007/10/02)
The hydrolytic cleavage of p-nitrophenyl alkanoates has been investigated in moderately alkaline aqueous solutions of α- and β-cyclodextrins.The catalytic effects of cyclodextrins (the kc/kun ratios) first decrease and then increase
