Chemistry Letters p. 159 - 162 (1985)
Update date:2022-07-29
Topics:
Ueno, Akihiko
Suzuki, Iwao
Hino, Yoshihiro
Suzuki, Atsuko
Osa, Tetsuo
γ-Cyclodextrin-catalyzed hydrolysis of p-nitrophenyl esters bearing a long alkyl chain proceeded with larger rate acceleration than those with a short alkyl chain.Such rate acceleration behavior was not observed with β-cyclodextrin.The results suggest that the esters with a long alkyl chain take a folded structure (Type A) in the γ-cyclodextrin cavity.
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