741198-63-0Relevant academic research and scientific papers
Application of the β-cyclodextrin supramolecules as a green accelerator hosts in one-step preparation of highly functionalised rhodanine scaffolds
Rostamnia, Sadegh,Doustkhah, Esmail,Hassankhani, Asadollah
, p. 1 - 3 (2015)
β-Cyclodextrin (β-CD) supramolecule was found to be a convenient, green and economical tool in one-pot synthesis of rhodanine scaffolds as a highly efficient mediating agent in aqueous media in which the reaction accelerated to complete in 15 min and room
Synthesis of novel dithiocarbamates and xanthates using dialkyl azodicarboxylates: S–N bond formation
Ziyaei Halimehjani, Azim,Klepetá?ová, Blanka,Beier, Petr
, p. 1850 - 1858 (2018/03/06)
A one?pot three?component route for the synthesis of a novel category of dithiocarbamates or xanthates is developed by a reaction of in-situ generated dithiocarbamic acids or xanthates with dialkyl azodicarboxylates under mild and catalyst-free conditions. The reaction is characterized by a wide scope, high efficiency and straightforward isolation protocol. The synthetic utility of the dithiocarbamates and xanthates was demonstrated on the preparation of symmetrical and unsymmetrical thioureas, isothiocyanates, and thiocarbamates.
The near infra red (NIR) chiroptical properties of nickel dithiolene complexes
Le Gal, Yann,Vacher, Antoine,Dorcet, Vincent,Fourmigu, Marc,Crassous, Jeanne,Lorcy, Dominique
, p. 122 - 129 (2015/02/19)
Enantiomerically pure dianionic, monoanionic and neutral dithiolene complexes formulated as [Ni((R,R)-CHMePh-thiazdt)2]-2,-1,0 and [Ni((S,S)-CHMePh-thiazdt)2]-2,-1,0 (CHMePh-thiazdt: N-(1-phenylethyl)-1,3-thiazoline-2-thione-4,5-dithiolate) have been synthesized from the enantiopure N-(1-phenylethyl)-1,3-thiazoline-2-thione precursors. The electrochemical and spectro-electrochemical investigations carried out on these complexes show that the CHMePh-thiazdt ligands act as electron rich ligands and that the complexes are strong near infrared (NIR) absorbers in the range of 800-1100 nm for the neutral species and 1050-1500 nm for the reduced radical anion species. Circular dichroism (CD) thin layer spectro-electrochemical experiments carried out on the neutral (R,R) enantiomer, [Ni((R,R)-CHMePh-thiazdt)2], revealed a redox switching of CD-active bands, not only in the UV-vis but also in the NIR region.
