741265-45-2

Upstream product

• 741265-63-4 2-(tert-butyl-diphenyl-silanyloxymethyl)-4,6-bis-methoxymethoxy-benzaldehyde 
• 741265-44-1 2-(tert-butyl-diphenyl-silanyloxymethyl)-6-hydroxy-4-methoxymethoxy-benzaldehyde 
• 741265-43-0 2-hydroxymethyl-4,6-bis-methoxymethoxy-benzaldehyde 
• 100-39-0 benzyl bromide 
• 79834-15-4 (2-bromo-3,5-bis(methoxymethoxy)phenyl)methanol 
• 558-13-4 carbon tetrabromide 
• 741265-64-5 2-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxymethoxy-benzaldehyde 

Downstream Products

• 741265-51-0 8-benzyloxy-3-(2-benzyloxy-6-formyl-4-methoxymethoxy-phenyl)-1,4-dimethoxy-naphthalene-2-carbaldehyde 

Relevant academic research and scientific papers

Concise total synthesis and structure assignment of TAN-1085

Rapid access to the tetracyclic core of TAN-1085 (1) was possible by exploiting three efficient processes: a tandem electrocyclic reaction (A), a pinacol cyclization (B), and a regioselective monobenzoylation of a 1,2-diol (C), which allowed the first total synthesis of 1.