74142-62-4Relevant academic research and scientific papers
Palladium Catalyzed Cyclization of 1,5-Bismethylenecyclooctane. Application to One Carbon Ring Enlargement
Heumann, A.,Reglier, M.,Waegell, B.
, p. 1971 - 1974 (1983)
1,5-Bismethylene cyclooctane 1 is transformed in a one pot multistep sequence to bridgehead substituted bicyclodecane derivatives by a catalytical PdII mediated oxidation reaction.A regioselective Wagner Meerwein rearrangement leading to ring enlargement is involved.The major product 5 can be fragmentated to a nine membered ring.
