Tetrahedron Letters p. 1971 - 1974 (1983)
Update date:2022-07-30
Topics:
Heumann, A.
Reglier, M.
Waegell, B.
1,5-Bismethylene cyclooctane 1 is transformed in a one pot multistep sequence to bridgehead substituted bicyclo<4.3.1>decane derivatives by a catalytical PdII mediated oxidation reaction.A regioselective Wagner Meerwein rearrangement leading to ring enlargement is involved.The major product 5 can be fragmentated to a nine membered ring.
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(1980)
