74205-53-1

Basic information

• Product Name: (2-Isopropoxy-phenyl)-acetonitrile
• CAS NO: 74205-53-1
• Molecular Weight: 175.23
• Mol File: 74205-53-1.mol

Chemical Properties

• CAS DataBase Reference: (2-Isopropoxy-phenyl)-acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Isopropoxy-phenyl)-acetonitrile(74205-53-1)
• EPA Substance Registry System: (2-Isopropoxy-phenyl)-acetonitrile(74205-53-1)

Safety Data

• Hazardous Substances Data: 74205-53-1(Hazardous Substances Data)

Upstream product

• 611-20-1 salicylonitrile 
• 773837-37-9 sodium cyanide 
• 540734-36-9 1-(chloromethyl)-2-(propan-2-yloxy)benzene 
• 82657-68-9 [2-(propan-2-yloxy)phenyl]methanol 
• 63635-26-7 2-isopropoxybenzoic acid 
• 90921-35-0 2-isopropoxybenzonitrile 

Downstream Products

• 61492-07-7 (2S,5R,6R)-6-{[1-(2-Isopropoxy-phenyl)-cyclopentanecarbonyl]-amino}-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 
• 61492-36-2 (2S,5R,6R)-6-{[1-(2-Isopropoxy-phenyl)-cyclobutanecarbonyl]-amino}-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 
• 61492-20-4 (2S,5R,6R)-6-{[1-(2-Isopropoxy-phenyl)-cyclopropanecarbonyl]-amino}-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 
• 74316-91-9 1-(2-Isopropoxy-phenyl)-cyclopentanecarboxylic acid 
• 74205-41-7 1-(2-Isopropoxy-phenyl)-cyclobutanecarboxylic acid 
• 74205-27-9 1-(2-Isopropoxy-phenyl)-cyclopropanecarboxylic acid 
• 74205-13-3 1-(2-Isopropoxy-phenyl)-cyclobutanecarbonitrile 
• 74204-99-2 1-(2-Isopropoxy-phenyl)-cyclopropanecarbonitrile 
• 74316-81-7 1-(2-Isopropoxy-phenyl)-cyclopentanecarbonitrile 

Relevant articles and documents

High diastereoselectivity in the yang photocyclization via remote hydrogen abstraction reaction

1-Benzoyl-1-(o-alkoxyphenyl)cyclopropanes undergo Yang photocyclization to form dihydrobenzopyranols in a stereospecific manner. The cyclopropyl group at alpha position to carbonyls gives not only a bias in the most stable geometries of the starting ketones but also conformational restriction on geometries of biradical intermediates. More importantly, intramolecular hydrogen bonds seem to give an additional effect on conformational control of the biradical reactivity.