742104-92-3Relevant academic research and scientific papers
Conformationally constrained analogues of diacylglycerol. 24. Asymmetric synthesis of a chiral (R)-DAG-lactone template as a versatile precursor for highly functionalized DAG-lactones
Kang, Ji-Hye,Siddiqui, Maqbool A.,Sigano, Dina M.,Krajewski, Krzysztof,Lewin, Nancy E.,Pu, Yongmei,Blumberg, Peter M.,Lee, Jeewoo,Marquez, Victor E.
, p. 2413 - 2416 (2007/10/03)
(Equation Presented) Commercially available 2-methylenepropane-1,3-diol was converted to chiral epoxide (R)-2 via Sharpless asymmetric epoxidation in >96% ee. Regiospecific epoxide ring opening and reduction of the intermediate alkyne set the stage for a
