74249-42-6Relevant academic research and scientific papers
An efficient methodology for the C-C bond forming radical cyclization of hydrophobic substrates in water: Effect of additive on radical reaction in water
Nambu, Hisanori,Anilkumar, Gopinathan,Matsugi, Masato,Kita, Yasuyuki
, p. 77 - 85 (2007/10/03)
The combination of the water-soluble radical initiator, 2,2′-azobis[2-(2-imidazolin-2-yl)propane] (VA-061), water-soluble chain carrier, 1-ethylpiperidine hypophosphite (EPHP) and surfactant, cetyltrimethylammonium bromide (CTAB), was found to be the most
A novel and efficient methodology for the C-C bond forming radical cyclization of hydrophobic substrates in water
Kita, Yasuyuki,Nambu, Hisanori,Ramesh, Namakkal G.,Anilkumar, Gopinathan,Matsugi, Masato
, p. 1157 - 1160 (2007/10/03)
Matrix presented The combination of water-soluble radical initiator 2,2′-azobis[2-(2-imidazolin-2-yl)propane] (VA-061), water-soluble chain carrier 1-ethylpiperidine hypophosphite (EPHP), and surfactant cetyltrimethylammonium bromide (CTAB) was found to b
The Reaction of Bis(dimethylglyoximato)(pyridine)cobalt(I), Cobaloxime(I), with 2-(Allyloxy)ethyl Halides and the Photolysis of the Resulting Organo-cobaloximes
Okabe, Masami,Tada, Masaru
, p. 1498 - 1503 (2007/10/02)
The reactions of 2-(allyloxy)ethyl halides with cobaloxime(I) gave (tetrahydro-3-furanyl)methylcobaloximes via an electron transfer from cobaloxime(I) to the halides to give radical anions.The rupture of a halide ion to give an organic radical and the ring closure to give a (tetrahydro-3-furanyl)methyl radical are followed by the radical coupling between the organic radical and the cobaloxime(II).The structures of the organocobaloximes were determined by the analyses of the photolysis products under aerobic or anaerobic conditions.
