74253-29-5

Upstream product

• 109-99-9 tetrahydrofuran 
• 1178-69-4 benzyl gibberellate 
• 1178-69-4 benzyl gibberellate 

Downstream Products

• 77732-51-5 7-chloro-10β-methoxycarbonyl-1β,8β-dimethylgibbane-1α,4aα-carbolactone 
• 77732-52-6 4β,7-dichloro-10β-methoxycarbonyl-1β,8β-dimethylgibbane-1α,4aα-carbolactone 
• 77732-56-0 7-chloro-10β-cyclohexylmethoxycarbonyl-1β,8β-dimethylgibbane-1α,4aα-carbolactone 
• 77732-56-0 7-chloro-10β-cyclohexylmethoxycarbonyl-1β,8α-dimethylgibbane-1α,4aα-carbolactone 

Relevant academic research and scientific papers

Reactions of 2-Chloro-NN-diethyl-1,1,2-trifluoroethylamine with Alcohols. Part 3. In the Presence of Lithium Chloride; Preparation of Chlorogibberellins

The reactions of gibberellin derivatives with 2-chloro-NN-diethyl-1,1,2-trifluoroethylamine in the presence of lithium chloride have been investigated in several different solvents.In all cases the bridgehead hydroxy-group was smoothly replaced by chlorin

BRIDGEHEAD SUBSTITUTIONS. PREPARATION OF 7-CHLORO-, 7-BROMO- AND 7-METHYLSULPHINYL-GIBBERELLINS

7-Hydroxygibberellins react with nucleophiles in the presence of fluoroamine to give bridgehead substitution products.