7431-33-6Relevant academic research and scientific papers
Synthetic models of the inactive Copper(II)-tyrosinate and active Copper(II)-tyrosyl radical forms of galactose and glyoxal oxidases
Halfen, Jason A.,Jazdzewski, Brian A.,Mahapatra, Samiran,Berreau, Lisa M.,Wilkinson, Elizabeth C.,Que Jr., Lawrence,Tolman, William B.
, p. 8217 - 8227 (2007/10/03)
A series of Cu(II) and Zn(II) complexes with new ligands having either one or two substituted phenolates appended to the 1,4,7-triazacyclononane frame were prepared and characterized by optical absorption, EPR, NMR, and/or resonance Raman spectroscopy, cy
Preparation of ortho-(alkyl-or arylthio) phenols
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, (2008/06/13)
Strong acids, e.g., aluminosilicates and sulfonic acids are employed as catalysts for the (alkyl or aryl)thiolation of phenols using dialkyl or diaryl disulfides and/or (alkyl- or arylthio)phenols as thiolating agents, and for the isomerization of (alkyl- or arylthio)phenols, to prepare ortho--(alkyl- or arylthio)phenols as the predominant products.
Preparation of ortho-(alkyl- or arylthio)phenols
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, (2008/06/13)
Strong acids, e.g., aluminosilicates and sulfonic acids are employed as catalysts for the (alkyl or aryl)thiolation of phenols using dialkyl or diaryl disulfides and/or (alkyl- or arylthio)phenols as thiolating agents, and for the isomerization of (alkyl- or arylthio)phenols, to prepare ortho(alkyl- or arylthio)phenols as the predominant products.
Process for the preparation of ortho-(hydrocarbylthio)-phenols
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, (2008/06/13)
Disclosed is a process for the preparation of otho-(hydrocarbylthio)-phenols, having at least one hydrogen on a carbon atom ortho to a hydroxy group, with hydrocarbyl disulfides in the presence of catalytic amounts of aluminum phenoxide.
