744-45-6Relevant articles and documents
A synthetic isophthalic acid diphenyl process (by machine translation)
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Paragraph 0015; 0016; 0017; 0018; 0019; 0020; 0021-0023, (2017/02/09)
The invention belongs to the field of organic synthetic technology, and in particular relates to a process for preparing phthalic acid diphenyl process. The isophthalic chloride with phenol as the main raw material, potassium carbonate as capture, dichloroethane or dichloromethane as solvent, in 10 °C to 50 °C conducted under the conditions of reaction synthesis of diphenyl-phthalic acid. The isophthalic chloride is dissolved in the solvent into the reactor at the same time add acid-binding (isophthalic chloride in solvent in the mass concentration of 8% — 15%), phenol also is dissolved in the solvent, through the dropping funnel into the reactor. Isophthalic chloride with phenol in a molar ratio of 1: 2.6 — 1: 2.0 between, potassium carbonate with the phenol in a molar ratio of 1.0: 1 - 1 .06: 1 between, to maintain the reaction 4 - 12 hours, to the reaction solution after the reaction is washed by water, liquid, distilling solvent, recrystallization and other steps, to obtain the isophthalic acid diphenyl finished product. After the distillation of the solvent recovered after drying can be recycled. (by machine translation)
Diphenyl isophthalate synthesis method with ethanol as solvent
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Paragraph 0011; 0012, (2016/11/21)
The invention relates to the field of fine chemicals, and relates to a dihenyl isophthalate synthesis method with ethanol as a solvent. According to the synthesis method, under a catalytic effect of a phase transfer catalyst benzyltriethylammonium chloride and with ethanol as a solvent, isophthaloyl chloride and phenol are subjected to a reaction; and high-purity diphenyl isophthalate is obtained through reduced-pressure distillation. With a direct esterification method, a reaction is not complete, and free acid group causes adverse influence on the next step of polymerization reaction. With a transesterification method, a product is colored. In traditional productions, phenol-containing wastewater is produced and is hard to treat. With the method provided by the invention, the above problems are overcome. The method is safe and environment-friendly, and is suitable for industrial productions. The dihenyl isophthalate provided by the invention has a chromatography content above 99.8%. A reaction average yield is higher than 98.70%.
Synthesis of esters with aromatic structure from aromatic carboxylic acids and diphenyl carbonate
Chiriac, Constantin I.,Onciu, Marioara,Tru?can, Ioan,Mihaela, Tanasa Fulga,Bǎdǎrǎu, Cristina
, p. 1065 - 1068 (2007/10/03)
Aromatic esters have been prepared with high to moderate yields from the corresponding aromatic carboxylic acids and diphenyl carbonate in pyridine at reflux (about 140-150 °), 5-6 hours.