74407-98-0Relevant academic research and scientific papers
Electrochemical behavior of amidine hydrochlorides and amidines
Daoust, Benoit,Lessard, Jean
, p. 362 - 374 (2007/10/03)
The electrochemical behavior of N,N-dimethyl-N'-phenylformamidine hydrochloride was studied on a platinum electrode.The oxidation peak at +0.90 V vs.Ag/Ag+ 0.01 M (in CH3CN - 0.1 M LiClO4) was assigned to the oxidation of the chloride anion.N,N
STEREOSPECIFIC FORMATION OF AMIDINES BY 1,1-ADDITION OF AMINES TO ISOCYANIDES
Hegarty, Anthony F.,Chandler, Anne
, p. 885 - 888 (2007/10/02)
Addition of secondary amines to isonitriles in the presence of AgCl at low temperature gives isolable but thermodynamically unstable Z-amidines; only the more stable 6E undergoes ring expansion to the imidazoline 7.
