74447-69-1

Basic information

• Product Name: 4-BROMO-3'-METHOXYBIPHENYL
• Synonyms: 4-BROMO-3'-METHOXYBIPHENYL;AKOS BAR-2329
• CAS NO: 74447-69-1
• Molecular Formula: C₁₃H₁₁BrO
• Molecular Weight: 263.13
• Mol File: 74447-69-1.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 132°C/0.1mm
• Flash Point: 140℃
• Appearance: /
• Density: 1.350
• CAS DataBase Reference: 4-BROMO-3'-METHOXYBIPHENYL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMO-3'-METHOXYBIPHENYL(74447-69-1)
• EPA Substance Registry System: 4-BROMO-3'-METHOXYBIPHENYL(74447-69-1)

Safety Data

• Hazardous Substances Data: 74447-69-1(Hazardous Substances Data)

Upstream product

• 53034-21-2 α-(4-bromophenylazo)triphenylmethane 
• 100-66-3 methoxybenzene 
• 2398-37-0 3-methoxyphenyl bromide 
• 589-87-7 1,4-bromoiodobenzene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 673-40-5 4-bromobenzenediazonium tetrafluoroborate 
• 10365-98-7 3-methoxyphenylboronic acid 
• 108-86-1 bromobenzene 
• 1003858-50-1 2-(3-methoxyphenyl)-5, 5-dimethyl-1,3,2-dioxaborinane 
• 6999-03-7 1-bromo-4-(trimethylsilyl)benzene 
• 106-37-6 1.4-dibromobenzene 

Downstream Products

• 149950-41-4 4'-bromo-[1,1'-biphenyl]-3-ol 
• 1373123-20-6 (3'-hydroxybiphenyl-4-yl)diphenylmethanol 
• 1373123-18-2 4-(2-hydroxyadamantan-2-yl)-3'-hydroxybiphenyl 
• 1373123-28-4 4-diphenylmethyl-3'-hydroxybiphenyl 
• 1373123-27-3 4-[(2-hydroxyethylamino)diphenylmethyl]-3'-hydroxybiphenyl 
• 1373123-24-0 4-[2-(2,2,2-trifluoroethoxy)adamantan-2-yl]-3'-hydroxybiphenyl 
• 1373123-37-5 4-(2-hydroxyadamantan-2-yl)-3'-methoxybiphenyl 
• 186550-26-5 3'-methoxy-[1,1'-biphenyl]-4-sulfonyl chloride 

Relevant articles and documents

Pyrazole-Mediated C-H Functionalization of Arene and Heteroarenes for Aryl-(Hetero)aryl Cross-Coupling Reactions

Herein we introduce a transition-metal-free protocol that involves a commercially available, inexpensive pyrazole molecule to conduct C-C cross-coupling reactions at room temperature via a radical pathway. Using this method, an aryldiazonium salt has been coupled to a wide range of arenes and heteroarenes including benzene, mesitylene, thiophene, furan, benzoxazole to result the corresponding biaryl products. The full reaction mechanism is elucidated along with the crystallographic probation of an active initiator species. A potassium-stabilized deprotonated pyrazole steers single-electron transfer to the substrate and behaves as an initiator for the reaction.

Gold-Catalyzed Oxidative Biaryl Cross-Coupling of Organometallics

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A process for preparing halogenated biphenyl (by machine translation)

A process for preparing halogenated biphenyl compound of the method, it is in order to aryl borate and aryl silane reagent as a raw material, 1, 1, 2 - trichloroethane as solvent, oxygenated esters of acetic acid as the oxidizing agent, paratoluene sulfonic acid silver as silver salts. In 110 °C lower, N - (diphenyl phosphate alkyl) - N - isopropyl - 1, 1 - diphenyl phosphine amine [...] 1 a catalytic cross-coupling, and efficient synthesis of aryl compounds of the halogenating is joint method. (by machine translation)