74457-36-6Relevant academic research and scientific papers
1-Silyl-1-boryl-2-alkenes: Reagents for stereodivergent allylation leading to 4-oxy-(E)-1-alkenylboronates and 4-oxy-(Z)-1-alkenylsilanes
Shimizu, Masaki,Kitagawa, Hirotaka,Kurahashi, Takuya,Hiyama, Tamejiro
, p. 4283 - 4286 (2007/10/03)
Silylboryl reagents for organic synthesis: 1-silyl-1-boryl-2-alkenes (2) were prepared efficiently by gem-silylborylation of α-chloroallyllithium compounds from (dimethylphenylsilyl) (pinacolato)borane (1; see scheme, LDA = lithium diisopropylamide) and w
An unusual example of a 1,1-cycloaddition reaction of a diazoalkane
Padwa, Albert,Ku, Hao
, p. 1009 - 1012 (2007/10/02)
Thermolysis of the sodium salt of E-1,4-diphenyl-3-buten-1-one N-tosylhydrazone gave rise to the corresponding diazoalkane which undergoes a subsequent 1,1-cycloaddition reaction to produce 3,6-diphenyl-1,2-diazabicyclo[3.1.0]hex-2-ene.
